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Ultra-high precision cavity refractometry for glass material studies

¡¡ The resonant frequency and intensity of an optical resonator critically depend on the round-trip optical path length and loss, and hence refractive indices and absorption of its constituent materials. In a high-Q optical resonator, even tiny optical property change can be readily resolved, a unique capability made possible by the resonantly enhanced photon-matter interactions. Based on this concept, we have pioneered a novel technique utilizing optical resonators to probe micro-structural evolution in glass materials, since structural modifications in these glasses are often accompanied by a refractive index and/or absorption change.

We have used this technique to systematically characterized chalcogenide glass thin films and extracted a wealth of information that is challenging or even impossible to obtain with traditional metrology tools. For example, in the As-S glass system, we have measured photo-induced refractive index change kinetics, two photon absorption (TPA) and thermo-optic coefficient with unprecedented accuracy [1]. We have also discovered several interesting new phenomena in this glass material that we will report shortly.

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¡¡ Schematic illustration of the photo-induced refractive index change measurement setup Photosensitivity as a function of exposure dose in as-deposited and annealed resonators
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¡¡ [1] J. Hu, N. Carlie, L. Petit, A. Agarwal, K. Richardson, and L. C. Kimerling, ¡°Demonstration of chalcogenide glass racetrack micro-resonators,¡± Opt. Lett. 33, 761-763 (2008); select for the Virtual Journal of Biomedical Optics 3 (5).